Term
| RCH2COOH -1)Br2,PBr3/2)H2O-> |
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Definition
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Term
| RCH2COOH -1)Br2,PBr3/2)H2O-> -NH3-> |
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Definition
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Term
| CH3C=ONHCH(COOCEt)2 -1)NaOEt/2)RX/3)H3O+-> |
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Definition
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Term
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Definition
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Term
| RCH=(COOH)NHCOCH3 (Z) -1)H2,[Rh(DiPAMP)(COD)]+/2)NaOH,H2O-> |
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Definition
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Term
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Definition
| Cleaves off N terminal peptide with (C6H5)-N=C=S |
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Term
| +NH3CHRCOO- +((CH3)3COC=O)2O -(CH3CH2)3N-> |
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Definition
| (CH3)3COC=ONHCHRCOO- (Amine protection) |
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Term
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Definition
| +NH3CHRCOOCH3 (Carboxyl protection) |
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Term
| +NH3CHRCOO- -PhCH2OH/HCl-> |
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Definition
| +NH3CHRCOOOCH2Ph (Carboxyl protection) |
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Term
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Definition
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Term
| RC=OH -NH4CN/H2O-> -H3O+/Heat-> |
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Definition
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Term
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Definition
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Term
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Definition
| 1)NaOH/2)H3O+ for CH3OH protected, H2/Pd for PhCH2OH protected |
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Term
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Definition
| Cleaves C-term of Phe, Tyr, and Trp (all aromatic) |
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Term
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Definition
| Cleaves C-term of Lys, and Arg (both basic) |
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Term
| 2 RSH -X2 or H2O2 or [O]-> |
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Definition
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Term
| RSSR -Zn,H+ or FADH2 or [H]-> |
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Definition
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Term
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Definition
| cleaves C-term amino acid |
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Term
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Definition
| tert-butoxycarbonyl amide |
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Term
| Coupling of protected amino acids (amide formation) |
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Definition
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Term
| Merrifield Solid-State Synthesis |
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Definition
| BOC-AA + ClCH2-Polymer -Base-> BOC-AA-CH2Poly -CF3CO2H-> AA-CH2Poly -DCC/BOC-AA'-> BOC-AA'-AA-CH2Poly -HF-> AA'-AA + FCH2Poly |
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