Term
| 1.O3/2.Zn,H2O (terminal alkene) |
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Definition
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Term
| PCC/CH2Cl2 (primary alcohol) |
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Definition
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Term
| AlCl3 (bezene + aldehyde hailide) |
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Definition
| Benzene + O=C-Cl -> Benzaldehyde |
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Term
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Definition
| propyne -> C-C-C=O (enol totomerism) |
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Term
| 1. DIBAH -78C toluene/ 2. H3O+ |
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Definition
| ester -> aldehyde + primary alcohol |
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Term
| 1.O3/2.Zn,H2O (tertiary alkene) |
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Definition
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Term
| KMnO4/H3O (tertiary alkene) |
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Definition
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Term
| PCC/CH2Cl2 (secondary alcohol) |
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Definition
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Term
| KMnO4/H3O+ (secondary alcohol) |
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Definition
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Term
| CrO3/acetone H3O+ (secondary alcohol) |
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Definition
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Term
| Na2Cr2O7/CH2CO2H (secondary alcohol) |
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Definition
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Term
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Definition
| keytone (enol totomerism) |
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Term
| AlCl3 (bezene + keytone hailide) |
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Definition
| Benzene + R-O=C-Cl -> Phenyl methanal |
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
| Aldehyde or Keytone + NaCN/HCN |
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Definition
| Nucliophilic addition 1-ol 1-CN |
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Term
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Definition
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Term
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Definition
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Term
| Aldehydes vs. Keytones (reactivity) |
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Definition
| Aldehydes more reactive. (steric hinderance, R- groups electron donating) |
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Term
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Definition
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Term
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Definition
| R-CH-OH-CH3 secondary alcohol |
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Term
| R-C=O-R' + 1.CH3MgBr/2.H3O+ |
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Definition
| R-C-OH-C-R' tertiary alcohol |
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Term
| R-C=O-O-C + 1.CH3MgBr/2.H3O+ |
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Definition
| Tertiary alcohol + Primary alcohol |
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Term
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Definition
| H2NNH2/KOH R-C=O-R' -> R-CH2-R' R-C=O-H -> R-CH3 |
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Term
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Definition
| HCl/Zn(Hg) R-C=O-R' -> R-CH2-R' R-C=O-H -> R-CH3 |
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Term
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Definition
| R-C=O-R' -> R-C=(NCH3)-R' |
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Term
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Definition
| R-C=O-R' -> R=C-N(CH3)2-R' |
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Term
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Definition
| R-C=O-R' -HCl/R"OH-> R-C-(OH)-(OR")-R' |
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Term
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Definition
| R-C=O-R' -HCl/excess R"OH-> R-C-(OR")-(OR")-R' |
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Term
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Definition
| R-C=O-R' -> R-C-O-R"-O'-(first C) cyclic |
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Term
| Protecting ketone from reduction |
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Definition
| To protect: HOROH/Hl To deprotect: H3O+ |
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Term
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Definition
| (Ph)3P+-C(-)R2 + R'-C=O-R" -> R"R'-C=CR2 |
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Term
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Definition
| Aldehyde -> Carboxilic acid (Tollen's reagent. Only works on aldehydes) |
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Term
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Definition
| Benzaldehyde -1.NaOH 2.Whatever you start with 3.H3O+-> Benzyl alcohol + Benzaldehyde |
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Term
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Definition
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Term
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Definition
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Term
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Definition
| 1.AgNO3, NH3/2.H3O+ On aldhydes only to carboxylic acid |
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