Term
| If PKa of conjugate acid is 11 or greater, |
|
Definition
| basicity is greater than nucleophilicity |
|
|
Term
| If PKa of conjugate acid is 11 or less, |
|
Definition
| nucleophilicity wins over basicity |
|
|
Term
| conjugate acid: CH4, CH2=CH2, HC(triplebond)CH, NH3 |
|
Definition
|
|
Term
| conjugate acid: CH3OH, H2O, |
|
Definition
|
|
Term
| conjugate acid: CH3SH, NH4+, HCN, H2S |
|
Definition
| nucleophilic (just under 11) |
|
|
Term
| conjugate acid: HN3, CH3OOH, H3O+, R-OH2+ |
|
Definition
| Nucleophilic (just under 11) |
|
|
Term
| conjugate acid: HF, HCl, HBr, HI |
|
Definition
| Nucleophilic (way under 11) |
|
|
Term
|
Definition
| Nucleophilic (way under 11) |
|
|
Term
| Good Nu/ Weak Base (Nu>B) |
|
Definition
I-, Br-
SH-, RS- (e.g. CH3S-)
CN-, N3-
PPh3, PH2- |
|
|
Term
| Moderate Nu/ Weak Base (Nu>B) |
|
Definition
Cl-, F-
RCOO- (e.g. CH3COO-)
RSH (e.g. CH3SH) |
|
|
Term
| Strong Nu/ Strong B (Nu>B) |
|
Definition
R- (e.g. CH3-)
HC---C-, R-C---C-, NH2- |
|
|
