Term
|
Definition
Alkyl Halides- Hydrohalogenation
[image] |
|
|
Term
|
Definition
|
|
Term
alkene --Br2/CH2Cl2 or CCl4
|
|
Definition
Halogenation trans- 1,2 dibromides
[image] |
|
|
Term
|
Definition
| Bromohydrin Formation- Trans 1,2-bromohydrins |
|
|
Term
|
Definition
Catalytic Hydrogenation
Alkanes |
|
|
Term
| alkene -- KMnO4, NaOH, or OsO4 |
|
Definition
Cis Hydroxylation
cis 1,2 diols |
|
|
Term
|
Definition
Oxidative Cleavage
ketones or acids |
|
|
Term
|
Definition
epoxide formation
epoxides |
|
|
Term
| alkyne-- H2 & lindlar catalyst |
|
Definition
catalytic hydrogenation
cis alkenes |
|
|
Term
|
Definition
catalytic hydrogenation
alkanes |
|
|
Term
|
Definition
deprotenation of terminal alkyne
acetylide anion |
|
|
Term
| aromatics-- X2, FeX3, or AlX3 |
|
Definition
Halogenation
halogenated aromatic |
|
|
Term
|
Definition
Nitration
Nitrated Aromatic |
|
|
Term
|
Definition
Sulfonation
sulfonated aromatic |
|
|
Term
| aromatics-- tertiary alkyl halide, FeX3 |
|
Definition
Alkylation
alkylated aromatic |
|
|
Term
| aromatics-- R-CO-CL, FeCl3, or AlCl3 |
|
Definition
Acylation
acylated aromatic |
|
|
Term
| Aromatic w/one benzylic hydrogen --KMnO4 |
|
Definition
Side chain oxidation
Benzoic Acid |
|
|
Term
| Nitroaromatics-- H2 & Pd/C or iron and tin reagents |
|
Definition
reduction of Nitroaromatics
Anilines |
|
|
Term
| 2nd or 3rd alkyl halide -- weak Nu (solvent) |
|
Definition
|
|
Term
| methyl, primary or secondary alkyl halide-- good Nu |
|
Definition
SN2
inversion of configuaration |
|
|
Term
| secondary or tertiary alcohol-- weak base |
|
Definition
E1
alkene at most substituted carbon |
|
|
Term
| alkyl halide- strong/bulky base |
|
Definition
E2
alkene/alkyne at most substituted carbon |
|
|
Term
| aldehyde -- NaBH4/MeOH or LAH/H30+ |
|
Definition
Reduction of Aldehydes
primary alcohol |
|
|
Term
| ketone -- NaBH4/MeOH or LAH/H30+ |
|
Definition
Reduction of Ketones
secondary alcohol |
|
|
Term
| Carboxylic acids/derivatives-- LAH H3O+ |
|
Definition
Reduction of Carboxylic acids/derivatives
primary alcohol |
|
|
Term
|
Definition
|
|
Term
| secondary alcohol -- PCC or CrO3 |
|
Definition
|
|
Term
| primary alcohol-- KMnO4 or CrO3 |
|
Definition
|
|
Term
2nd-3rd alkyl halide or alcohol
-- H2SO4 or H3PO4 |
|
Definition
|
|
Term
| primary or 2nd alcohol -- isobutylene gas&acid catalyst |
|
Definition
t-butyl ether synthesis
t-butyl ether |
|
|
Term
|
Definition
ether cleavage
alkyl bromide or iodide/alcohol |
|
|
Term
|
Definition
|
|
Term
|
Definition
Synthesis of Alkyl Bromides
Alkyl bromides |
|
|
Term
|
Definition
Synthesis of Alkyl
Alkyl Chlorides |
|
|
Term
| alcohols-- tosyl chloride |
|
Definition
synthesis of tosylates
tosylates |
|
|
Term
| Aldehyde or Ketone-- Alcohol, H+ |
|
Definition
Hemiacetal/Acetal Formation
Hemiacetal/Acetal |
|
|
Term
| Aldehyde or Ketone-- primary amine, H+ |
|
Definition
|
|
Term
| Imines-- H2 and Pd/C or NaBH4 |
|
Definition
|
|
Term
| Ethylene Oxide-- a.)RMgBr/ether b.) H3O+ |
|
Definition
Alcohol Synthesis- Grignard
primary alcohol w/2C's |
|
|
Term
| Aldehydes-- a.)RMgBr/ether b.) H3O+ |
|
Definition
Alcohol Synthesis- Grignard
Secondary alcohol |
|
|
Term
| Formaldehyde-- a.)RMgBr/ether b.) H3O+ |
|
Definition
Alcohol Synthesis- Grignard
primary alcohol w/1C's |
|
|
Term
| Ketones-- a.)RMgBr/ether b.) H3O+ |
|
Definition
Alcohol Synthesis- Grignard
tertiary alcohol |
|
|
Term
| CO2-- a.)RMgBr/ether b.) H3O+ |
|
Definition
Alcohol Synthesis- Grignard
Carboxylic acid |
|
|
Term
|
Definition
| Formation of Acid Chloride |
|
|
Term
| Acid Chloride-- Carboxylate anion |
|
Definition
|
|
Term
| Carboxylic acid and alcohol -- acid catalyst |
|
Definition
|
|
Term
|
Definition
Hydrolysis
Carboxylic Avid/Amine |
|
|
Term
|
Definition
Hydrolysis
carboxylic acid and alcohol |
|
|
Term
|
Definition
syn. of alcohols
primary alcohol |
|
|
Term
| ester-- RMGBr/ether and H3O+ |
|
Definition
syn. of alcohols
tertiary alcohol |
|
|
Term
|
Definition
hydrolysis
carboxylic acid |
|
|
Term
|
Definition
hydrolysis
carboxylic acid |
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
Hydrolysis
carboxylic acid and amine |
|
|
Term
|
Definition
|
|
Term
| methyl, primary or secondary alkyl halide-- NaCN |
|
Definition
|
|
Term
|
Definition
Hydrolysis
carboxylic acid |
|
|
Term
|
Definition
|
|
Term
| Ketone or Aldehyde-- X2/HX |
|
Definition
Alpha Halogenation
alpha halogenated aldehyde or ketone |
|
|
Term
|
Definition
syn. of carboxylic acids, Haloform
Carboxylate Anion |
|
|
Term
| aldehdes or ketones--NaOH & EtOH H3O+ |
|
Definition
Aldol
alpha,beta unsaturated compound (enone or enal) |
|
|
Term
|
Definition
|
|
Term
| B-Keto ester -- a.) NaOEt, EtOH; b.) R-X H3O+ &heat |
|
Definition
Acetoacetic Ester Synth.
substituted ketones |
|
|
Term
| Beta-di ester-- a.) NaOEt, EtOH; b.) R-X H3O+ &heat |
|
Definition
Malonic Ester Synth.
substituted acids |
|
|
Term
| a,b-unsaturated compound and nucleophile --?? |
|
Definition
Michael RXN
new bond at Beta carbon |
|
|
Term
| carbonyl compound with a-hyrdogen--base |
|
Definition
formation of enolate
enolate |
|
|
Term
| carbonyl compound with a-hyrdogen-- acid |
|
Definition
|
|
Term
| alkene-- a.) mcpba b.) acid or base (aq) |
|
Definition
formation of trans diols (epoxide ring opening)
trans diol |
|
|
