Term
| How to add Br/Cl/I to a benzene |
|
Definition
|
|
Term
| how to add a propane to a benzene |
|
Definition
1 propane+=O+Cl on the end near O, and AlCl2
2 H2N2H2 NaOH |
|
|
Term
| How to add propane and Br meta |
|
Definition
| add Br before reducing to propane |
|
|
Term
| how to add propane and Br ortho/para |
|
Definition
| Br or propane steps can go first, as long as propane steps are concerted |
|
|
Term
| what is propane+=O+CL/BR called? What does it make with AlCl/Br2 |
|
Definition
|
|
Term
| how does C-C-C=O-Benz direct? |
|
Definition
|
|
Term
| how to add NO2 to benzene |
|
Definition
|
|
Term
| how to add CH=O to a benzene |
|
Definition
|
|
Term
| Is NO2 activating or deactivating? |
|
Definition
|
|
Term
|
Definition
| donating electrons, making benzene a better nucleophile |
|
|
Term
| withdrawing groups are ... |
|
Definition
| withdrawing electrons, making benzene a better electrophile |
|
|
Term
| for NAS the _____ group needs to be in the _____ position |
|
Definition
|
|
Term
| NH2 OCH3 OH are examples of reagents requiring.... |
|
Definition
|
|
Term
|
Definition
|
|
Term
| how does a benzyne react? |
|
Definition
| NH2 binds, negative on other side of bond, prots |
|
|
Term
| direct bond from benzene to O means... |
|
Definition
|
|
Term
| MnO4 (permanganate) makes a ____ coming off a benzene |
|
Definition
|
|
Term
| how to add Br to an alkane |
|
Definition
|
|
Term
| How to replace a Br with an OH |
|
Definition
|
|
Term
| to get an elimination, use reagent |
|
Definition
|
|
Term
| to replace Cl with a bulky R group |
|
Definition
|
|
Term
|
Definition
|
|
Term
| KMnO4 (or NaCrO), Heat, H3O makes ... |
|
Definition
| coming off C next to benzene (kill others), add OOH. (not on 4 prime) |
|
|
Term
| MnO2, heat (or PCC)turns OH to |
|
Definition
|
|
Term
| in general, Pd/C and H2 ... |
|
Definition
| get rid of oxygen and turn N's to NH2 (eg - NO2 to H2N) |
|
|
Term
to an NO2, add :
Sn, HCl, OH
NAOH |
|
Definition
|
|
Term
| getting rid of a C=O uses... |
|
Definition
Zn or Hg, HCl & heat
or
N2H4, OH, and heat (but will also replace CL with OH) |
|
|
Term
| H2 and Ni turn a C=O into... |
|
Definition
|
|
Term
| if a compound has 4 pi electrons it is... |
|
Definition
|
|
Term
| What is the fastest Sn1 reaction? |
|
Definition
| one which goes through an aromatic intermediate. |
|
|
Term
|
Definition
|
|
Term
what are the solfonation reagents ?
SO3H+ |
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| deactivating OP directors |
|
Definition
|
|
Term
| what's the general form for a deactivating meta group? |
|
Definition
|
|
Term
| name the super-deactivators (meta) |
|
Definition
|
|
Term
| when a 2nd sub is added Ortho, the positive charge begins... |
|
Definition
|
|
Term
| when a 2nd sub is added meta, the positive charge starts out... |
|
Definition
|
|
Term
| when a 2nd sub adds para, the positive charge starts out ____ to the 1st sub |
|
Definition
|
|
Term
MgBr off of a benzene +
1. CO2
2. H3O |
|
Definition
|
|
