Term
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Definition
| used for the formation of a double bond on the most substituted carbon |
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Term
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Definition
| bulky base puts the double bond on the least substituted carbon |
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Term
| strong acid like H3O+ and H2SO4 |
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Definition
| dehydrate and put the carbocation or the double bond on the most stable carbon |
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Term
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Definition
| creates a vic dihalide syn addition |
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Term
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Definition
| adds a bond to forcing of a leaving group |
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Term
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Definition
| this adds 2 chlorines to a carbon with a double bonded oxygen |
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Term
3 equiv. NaNH2
minerol oil, heat, HA |
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Definition
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Term
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Definition
| removes a H from a terminal alkyne |
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Term
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Definition
| turns alkyne, alkene into alkane |
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Term
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Definition
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Term
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Definition
| the H goes to the least substituted carbon, while the carbocation forms at the other and the X is added |
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Term
(1)Hg(OAc)2/THF-H2O
(2)NaBH4,OH- |
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Definition
Oxymercuration, Demercuration
puts a alcohol group on the most substituted alcohol |
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Term
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Definition
| puts the alcohol on the least substituted carbon |
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Term
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Definition
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Term
(1)OsO4,Pyridine
(2)NaHSO3/H2O |
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Definition
| adds alcohols in a syn addition |
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Term
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Definition
| adds alcohols in a syn addition |
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Term
(1)O3,CH2Cl2, -78
(2) Me2S |
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Definition
| cleaves an alkene and puts a double bonded oxygen on the spot of cleavage |
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Term
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Definition
| leaving group in the anti-Markovnikov place |
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Term
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Definition
| Puts a leaving group in the Markovnikov addition |
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Term
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Definition
| remove the poor leaving group...OH...and add a good leaving group |
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Term
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Definition
| removes a hydrogen from the alcohol to make it a good leaving group |
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Term
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Definition
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