Term
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Definition
| removes OH forms double bond |
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Term
|
Definition
| Adds OH removes double bond |
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Term
|
Definition
| replaces OH with OTS but does not effect stereo chemistry |
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Term
|
Definition
| replaces X with CN switches stereochem |
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Term
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Definition
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Term
|
Definition
| alleviates double bond adds on a Br's trans |
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Term
|
Definition
| removes Br and forms alkyne |
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Term
|
Definition
| adds the bottom except I to alyne |
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Term
|
Definition
| turns alkyne into cis alkene |
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Term
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Definition
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Term
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Definition
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Term
|
Definition
| turns alkyne into keytone and CH3 |
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Term
|
Definition
| turns alkyne into alkene and Br |
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Term
|
Definition
| alleviates triple bond and adds Br's |
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Term
|
Definition
| alleviates tripple bond and adds 4 Br's |
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Term
|
Definition
| breaks in half at alkyne and adds COOH to each end |
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Term
|
Definition
| alleviates alkene adds OH |
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Term
|
Definition
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Term
|
Definition
| halogen attached to benzene |
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
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Definition
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Term
|
Definition
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Term
|
Definition
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Term
|
Definition
| aromatic one because it is the most stable because the carbocation can be easily formed |
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|
Term
| thermodynamically favorable |
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Definition
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Term
|
Definition
| pentagon with two double bonds and an oxygen |
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Term
|
Definition
| aromatic compounds are more acidic because their conjugate acid is close to that of the pka of water |
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|
Term
| benzene rings and stability |
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Definition
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Term
|
Definition
| pentagon with two double bonds and a NH |
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Term
|
Definition
| pentagon with two double bonds and a S |
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Term
| How to tell if lone pairs are orthogonal |
|
Definition
| lone pairs part of double bond are orthogonal |
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Term
| stabilizing factors in order of stability for alkene functionalities |
|
Definition
-conjugation
-substitution
-isolation
-cumulene |
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|
Term
| acid catalyzed dehydration stablilizing factors in order of stabilization |
|
Definition
-tertiary carbocation
-doublly allylic
-allylic
-secondary
-primary |
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Term
| what is needed with molecular orbitals for a reaction to occur |
|
Definition
| overlap of the HOMO and LUMO |
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Term
|
Definition
| replaces halogen with OAC |
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Term
|
Definition
| cleaves double bond into single bond and adds Br |
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Term
|
Definition
| adds br to other side of double bond one away or adds to the top of double bond and moves double bond down one |
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|
Term
| COOEt-c(tripple bond)c-Br |
|
Definition
| forms hexagon, moves double bond to middle and one on opposite side, adds COOEt and Br to each end |
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Term
|
Definition
| moves double bond to middle, forms bar |
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Term
|
Definition
| lowest energy (empty orbital) |
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Term
|
Definition
| highest energy (most outer full orbital) |
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Term
|
Definition
| attaches COOH to sp3 carbons |
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Term
|
Definition
| adds NO2 (carbocation intermediate) |
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Term
|
Definition
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Term
|
Definition
| removes OH and adds Br for primary and secondary alcohols |
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