Term
| carboxylic acids are a good starting material for what? |
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Definition
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Definition
| acid chlorides, esters, amides, and thioesters |
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| suffix for carboxylic acids? |
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Definition
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| suffix for carbonyl grp bonded to an aromatic ring? |
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Definition
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Definition
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| Nitriles contain which functional group? |
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Definition
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| Chemistry of nitriles is similar to? |
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Definition
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Term
| suffix for open chained nitrile? |
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Definition
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Term
| -ic acid/-oil acid nitrile suffix? |
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Definition
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Term
| -carboxylic acid nitrile suffix? |
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Definition
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Term
| hybridization of carbonyl C? |
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Definition
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Term
| carboxylic acids have high/low boiling points because of? |
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Definition
| high bp because of hydrogen bonding |
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Term
| carboxylic acids defining characteristic is their? |
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Definition
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| carboxylic acids react with bases to give ? |
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Definition
| carboxylate salts (water soluble) |
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Definition
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| which is more acidic? carboxylic acids or alcohols? |
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Definition
| carboxylic acids are more acidic |
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Term
| carboxylic acids in acidic solution at low pH? |
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Definition
| carboxylic acid undissociated and exists as RCO2H |
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Term
| carboxylic acids in basic sol'n at high pH? |
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Definition
| carboxylic acid dissociates and exists as RCO2- |
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Term
| chlorine atom is EDG/EWG? |
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Definition
| EWG (more Cl= more acidic & closer Cl to carbonyl grp= more acidic) |
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Definition
| CH3, OCH3, OH (EDG & decrease acidity) |
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Definition
| NO2, CN, CHO, Br, Cl (EWG & increase acidity) |
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Term
| how to make a carboxylic acid from tertiary alkyl halide? |
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Definition
1- grignard (Mg, ether)
2- carboxylation (CO2, ether)
3- protonation (H3O) |
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