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| aldehydes and ketones undergo nucleophilic_____ while carboxyllic acid undergoes _______ |
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| aldehydes and ketones larger than 4 carbons are ______ |
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| keto-enol tautomerization involves the shifting of? |
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| protons from alpha carbo to carbonyl oxygen, an equillibrium reaction. |
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| electron withdrawing groups attached to the alpha carbon or carbonyl tend to _____ |
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| stabilize the conjugate base and increase acidity |
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| why are aldehydes more reactive than ketones? |
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| electron withdrawing effects of the ketone make it less reactive, and the inductive effects of the oxygen. |
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| purpose of the wittig reaction? |
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| ketone---> alkene using a phosphorous ylide |
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| carboxyllic acids with more than _____ are insoluble in water |
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| loss of co2 from carboxyllic acid |
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| very reactive because of stable halogen, strong acid,. |
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| ammonia and amines can ____ which increases their boiling points and increases their solubilities |
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| wolff kishner reduction does what to what |
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| reduces ketones and aldydes |
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a process where an amine is reacted to create a tertiary amine and an alkene
it is an E2 rxn that converts an amine into an alkene. it forms least substiuted double bond.
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| diazotization of an amine only works with? |
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aka hoffman degradation
the organic reaction of a primary amide to a primary amine with one fewer carbon atom |
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