Term
|
Definition
| concerted (1-step, no intermediate), back-side attack |
|
|
Term
|
Definition
| concerted (1-step, no intermediate), anti-coplanar |
|
|
Term
|
Definition
| 2-steps with carbocation intermediate |
|
|
Term
|
Definition
| 2-steps with carbocation intermediate |
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|
Term
|
Definition
rate is second order
rate = k[Nuc][RX] |
|
|
Term
|
Definition
rate is second order
rate = k[Nuc][RX] |
|
|
Term
|
Definition
rate is first order
rate = k[RX] |
|
|
Term
|
Definition
rate is first order
rate = k[RX] |
|
|
Term
| SN2: type of nucleophile/base |
|
Definition
|
|
Term
| SN1: type of nucleophile/base |
|
Definition
|
|
Term
| E2: type of nucleophile/base |
|
Definition
|
|
Term
| E1: type of nucleophile/base |
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
|
Definition
|
|
Term
| SN2: possibility of rearrangements |
|
Definition
| impossible b/c there is no carbocation intermediate |
|
|
Term
| E2: possibility of rearrangements |
|
Definition
| impossible b/c there is no carbocation intermediate |
|
|
Term
| SN1: possibility of rearrangements |
|
Definition
| carbocation intermediate may rearrange into more stable carbocation using hydride shifts or methyl shifts |
|
|
Term
| E1: possibility of rearrangements |
|
Definition
| carbocation intermediate may rearrange into more stable carbocation using hydride shifts or methyl shifts |
|
|
Term
| E2: orientation of alkene |
|
Definition
Zaitsev product (most-substituted alkene) results from unhindered base
Hofmann product (less-substituted alkene) results from sterically hindered base |
|
|
Term
| E1: orientation of alkene |
|
Definition
Zaitsev product (most-substituted alkene) results from unhindered base
Hofmann product (less-substituted alkene) results from sterically hindered base |
|
|
Term
|
Definition
| inversion of configuration |
|
|
Term
|
Definition
| inversion & retention of configuration |
|
|
Term
|
Definition
| no special geometry required |
|
|
Term
|
Definition
| anti coplanar transition state required |
|
|
Term
|
Definition
wide variety of solvents;
polar aprotic solvents will increase nucleophilicity |
|
|
Term
|
Definition
| good ionizing solvent needed |
|
|
Term
|
Definition
|
|
Term
|
Definition
| good ionizing solvent needed |
|
|
